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Another salinity factor beyond soluble salts is the Sodium
concentration and the Sodium Absorption Ratio or SAR.
Sodium is an essential element for some plants such as celery and
spinach, but most greenhouse and nursery crops have minimal sodium
requirements. The SAR is a calculated value that indicates the
relative concentration of sodium to that of calcium and magnesium in
a water. Irrigation with waters having an SAR above 4 can result in
root absorption of toxic levels of sodium, but this problem can be
prevented by the addition of calcium. Water containing greater than 3
meq/L sodium should not be used for overhead irrigation of
ornamentals and greenhouse plants as foliar absorption of sodium can
lead to sodium toxicity in sensitive species. Sodium toxicity,
whether due to root absorption or foliar absorption of Na, is
expressed as marginal leaf burn on older foliage.
The final salinity factor of concern is Chloride
concentration. Though it not usually listed as an essential
micronutrient, chlorine (as chloride) is needed in small quantities
by plants. However, in excess, greater than 2 meq/L, chloride can
become a production problem. The principal effect of too much
chloride (Cl- ) is an increase is the osmotic pressure of
the substrate solution that can reduce the availability of water to
plants and lead to wilting. High chloride levels can also lead to
toxicity symptoms in container production. When absorbed by plant
roots, the chloride ion is transported to leaves, where it
accumulates. Some species, such as roses, azaleas, camellias, and
rhododendrons develop leaf edge burn, leaf necrosis, and leaf
abscission when too much chloride is accumulated.
Macro Elements. The macro elements Nitrogen
(N), Phosphorus (P), Potassium (K), Calcium
(Ca), Magnesium (Mg), and Sulfur (S) are elements
essential for plant growth, and at moderate levels will not cause
production problems. However, content of these elements should be
evaluated as an indicator of potential contamination of the water
(for N, P, and K) as well as an indicator of fertilizer requirements
(for Ca, Mg, and S).
For example, nitrogen levels greater than 10 ppm are rarely found
in North Carolina waters. If your water contains greater than 10 ppm
N, there is a strong possibility that the water has been contaminated
with a fertilizer or other contaminant. If there is greater than 1
ppm of phosphorus and / or 10 ppm potassium, the water may be
contaminated with fertilizer, detergent, or some other contaminant.
Although these nutrient levels should not hinder plant growth, the
possibility of contamination should be further investigated, and the
water should not be used for human or livestock consumption if
concentrations of N, P, and K exceed the upper limits listed in Table
1.
Calcium and magnesium are normally found in North Carolina waters
in the ranges given in Table 1. It is acceptable to use water
containing the highest levels of Ca and Mg listed, if you reduce the
amount of calcium and magnesium supplied in the fertilizer program
and if the ratio of calcium to magnesium in your water source is
within acceptable limits.
What is an acceptable Ca : Mg ratio in an irrigation water? The
calcium and magnesium ratio in the substrate solution (and in the
irrigation water) should be 3 Ca to 1 Mg if expressed as meq/L or 5
Ca to 1 Mg if expressed as ppm Ca and Mg. There is a fairly wide
latitude of variance around these ratios. However, if the ratio
shifts a great deal from this, a deficiency of the nutrient which is
undesirably low in the ratio will occur. The more common problem is a
low level of magnesium relative to calcium. In this case it is
necessary to supplement occasionally with a Mg source such as
magnesium sulfate (Epsom salts). Examine the ratio of calcium to
magnesium (Ca : Mg) in your water to anticipate whether the substrate
Ca : Mg will tend to shift out of the desired range.
Sulfur concentrations in North Carolina waters are usually less
than 25 ppm, and excessive sulfur is not a normal problem. Table 1
lists recommended levels of sulfur for best plant growth. Usually,
growers must add additional sulfur to reach these recommended
application rates.
Micro Elements. Waters can contain small
concentrations of Aluminum (Al), Boron (B),
Copper (Cu), Fluoride (F- ), Iron (Fe),
Manganese (Mn), Molybdenum (Mo), and Zinc (Zn).
With the exception of Al and F-, these elements are
essential to plant growth and are required in small quantities.
Aluminum in irrigation water is rarely found in concentrations
high enough to lead to toxicities, and should not be a major concern
for most growers.
Among the specific plant micronutrients found in water, boron can
be particularly troublesome. A concentration of 0.5 ppm (mg/L) is
safe for any irrigation use. A level greater than 0.5 ppm is above
the upper limit and could lead to toxicity symptoms in
boron-sensitive crops. Boron toxicity can first show up as
orange-brown necrosis along the margins of older leaves. Flecking can
also occur on the underside of leaves.
Other micronutrients that can be excessive in irrigation water are
iron, manganese, zinc, and copper. Check levels and assure that
concentrations are below the levels listed in Table 1 prior to using
water. Micronutrient toxicities are more probable when the pH of the
substrate solution is low, rendering the micronutrients more
available for plant uptake. If the water source does contain high
concentrations of these micronutrients, adjustments in the
fertilization program should be made to prevent an overabundance of
the elements.
Fluoride is often added to municipal water at a concentration of 1
ppm to prevent tooth decay. This level is safe for most crops but not
for members of the lily family such as the genera Chamaedorea,
Chlorophytum, Ctenanthe, Dracaena, Marantha, Spathiphyllum and a
few other plants. Toxic levels of fluoride causes scorch of the tips
of older leaves.
Harmful Organisms. Iron Fixing Bacteria in
irrigation water can lead to many problems, including a bluish sheen
on plant surfaces and brown stains on plants. The blue and brown
deposits are two separate water quality problems both related to high
iron content in irrigation water applied by overhead irrigation
systems. The bluish bronze sheen is due to iron bacteria. They occur
naturally in the soil and can be a problem in well and basin
irrigation sources. In wells they often gum submersible pumps and
cause them to need replacement. On basins, the oily sheen over the
surface of the water is due to iron bacteria. They keep the iron in
the water from settling out so when irrigation goes over plants so
does the bluish iron deposit. In propagation houses you also can see
a slimy yellowish mass that plugs nozzles. That is the iron
bacteria.
The red-brown deposit is iron. Well water containing iron can be
pumped into basins and some of the iron will settle out, but if you
have iron bacteria it confounds the problem. One very important item
to check is the irrigation intake. Growers have avoided or reduced
the problem of iron deposits by making sure that their irrigation
intakes are 18 to 30 inches below the surface of the water. They need
to be at least 18 inches deep to prevent vortexing from the surface.
Intakes too close to the bottom pull settled iron sediment off the
bottom. Checking the location of the intake is difficult, but it is
worth the effort.
If raising or adjusting the intake is not the answer, then the
next choices become more expensive. The first step is to have the
water analyzed at a laboratory such as NCDA (Agronomic Division N.C.
Soil Testing Lab 4300 Reedy Creek Road, Raleigh, N.C. 27607; Phone
919.733.2655). Most labs need at least 16 ounces of water, so a clean
plastic drink bottle sample will be fine. Water analysis at the NCDA
lab costs $4.00. Although less than 0.5 ppm iron in water can stain
risers and coat plants, 0.5 to 3 ppm is common in irrigation water in
N.C. A foliar sample from coated plants would also be good to see how
much deposit is ending up on the plants.
Employ the following methods to control iron and iron bacteria
deposits:
If the iron content is high enough to cause problems as
indicated by the irrigation water test, the first step might be to
consider a basin aeration pump. This pump just keeps the water
moving and the ripples help precipitate iron and also help reduce
the iron as a food source for the iron bacteria. The wave action
is what adds air to the water, so a big pump creating a high
fountain is not necessary. The wave action also helps keep algae
and iron bacteria pushed up into coves of basins so try to locate
the aeration pump where it will give the most benefit in relation
to the location of the irrigation intake.
The next step to consider after installing an aerifier is
injection and probably filtration. Chlorine is often the material
of choice as a disinfectant and oxidizing agent. Chlorine is
injected into irrigation lines and usually requires some
retrofitting of the irrigation system. To be effective the
chlorine requires a one minute contact time in the irrigation
water to kill iron bacteria or have an oxidizing effect to change
Ferrous ( Fe++ ) to Ferric (Fe+++ ).
Chlorination eliminates the food source for the iron bacteria and
also eliminates both types of iron deposits on surfaces irrigated.
Usually storage tanks, swirl chambers or extra loops in the
irrigation lines are required for adequate contact time (a minimum
of 0.5 ppm for about 1 minute). Chlorination is usually
accomplished by gas or liquid injection. Gas chlorination is the
most efficient and effective method but is also dangerous. Liquid
chlorine injection is a safer alternative. Both systems are used
at nurseries in North Carolina and there are commercial irrigation
contractors who can install these systems. Chlorine gas is
injected from cylinders and the greatest danger occurs when
cylinders have to be changed, particularly if the cylinders are
housed in a building. Liquid chlorine (16% Sodium hypochlorite) is
usually purchased in 50 gallon drums and injected like other
liquids but the injector usually needs to be a variable ratio
injector because over time the 16% sodium hypochlorite loses
strength and the injection rate must be increased. Free chlorine
is checked using a swimming pool test kit at the end of the
irrigation line or riser and if the sample turns slightly, pink
indicating 1 to 3 ppm, the job is getting done. The chlorine kills
iron bacteria. To reduce the amount of chlorine injected, removal
of organic residue is recommended, which requires filtration.
Usually sand media filters are installed and two media filters
generally are recommended so one can be backflushed while the
other filter operates during irrigation. The cost for a
chlorination and filtration system will be around $5,000.
Other materials can also be injected. There are some products
made for drip and micro-jet irrigation systems that contain
sequestering agents, algaecides, bactericides, detergents and
stabilizing agents. Filtration might not be necessary with these
materials. By name, products such as Di-Solv, Aqua-Solv, and
Nurserymen's Pride (Flo Tec Associates, Inc., 2151 34th Way N,
Largo Fl, 34641 Phone 813.531.8796; FAX 813.530.0208) are sold for
nursery and horticultural uses. Nurserymen's Pride was developed
to clean and brighten foliage by removing dirt and chemical
residues; Aqua-Solv sequesters ions in irrigation water. Like
other materials, effective application depends upon equipment
available and concentration of iron or other problem mineral
content. Di-Solv prevents oxidation of the ferrous iron and
reduces staining. Di-Solv claims that when used over time, it will
clean up plants coated with iron. Citric acid and dish washer
detergent will also clean plant foliage, but for large volumes of
water these products will be more expensive than other materials
mentioned.
An approximate rate is 1 cup of dish washer detergent (like
Calgon) and
1/4 pound
citric acid per 5 gallons of solution. Citric acid can be
purchased from suppliers such as Worth Chemical, Durham, N.C.
Phone 919.596.1386. The cost of 50 pounds of citric acid (50
pounds per 1000 gallons of cleaning solution) is about $50.00.
W.A. Cleary Chemical Corporation (1049 Somerset St. Somerset N.J.
08873 Phone 201.247.8000) sells a Water Acidifier and Chelation
Agent which is formulated with the dual purpose of neutralizing
water alkalinity and chelating elements such as iron and
magnesium, making them available for both foliar and root
absorption. It is used with pesticide sprays which are more
effective in slightly acid water and where alkaline waters reduce
the effective half-life of a pesticide. The active ingredient of
this Water Acidifier and Chelation Agent is citric acid.
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